@article {44612,
	title = {Organocatalyst bound -aminoalkyl radical intermediate for controlled aerobic oxidation of iminium ions},
	journal = {Organic \& Biomolecular Chemistry},
	volume = {16},
	year = {2018},
	month = {JUL},
	pages = {5081-5085},
	abstract = {<p>A catalyst bound -aminoalkyl radical intermediate from iminium is developed to control its formation and reactivity with aerobic oxygen. The influence of the catalyst was demonstrated via the ease of radical intermediate formation and its subsequent reactivity, including the first catalyst-controlled enantioselective aerobic oxidation with a chiral phosphite catalyst.</p>},
	issn = {1477-0520},
	doi = {10.1039/c8ob01032c},
	author = {Motaleb, Abdul and Bera, Asish and Maity, Pradip}
}
@article {47594,
	title = {Phosphite mediated asymmetric N to C migration for the synthesis of chiral heterocycles from primary amines},
	journal = {Chemical Science},
	volume = {12},
	year = {2021},
	month = {JUL},
	pages = {8996-9003},
	type = {Article},
	abstract = {A phosphite mediated stereoretentive C-H alkylation of N-alkylpyridinium salts derived from chiral primary amines was achieved. The reaction proceeds through the activation of the N-alkylpyridinium salt substrate with a nucleophilic phosphite catalyst, followed by a base mediated [1,2] aza-Wittig rearrangement and subsequent catalyst dissociation for an overall N to C-2 alkyl migration. The scope and degree of stereoretention were studied, and both experimental and theoretical investigations were performed to support an unprecedented aza-Wittig rearrangement-rearomatization sequence. A catalytic enantioselective version starting with racemic starting material and chiral phosphite catalyst was also established following our understanding of the stereoretentive process. This method provides efficient access to tertiary and quaternary stereogenic centers in pyridine systems, which are prevalent in drugs, bioactive natural products, chiral ligands, and catalysts.},
	issn = {2041-6520},
	doi = {10.1039/d1sc01217g},
	author = {Rani, Soniya and Dash, Soumya Ranjan and Bera, Asish and Alam, Md Nirshad and Vanka, Kumar and Maity, Pradip}
}
@article {48726,
	title = {C-H functionalization of pyridines},
	journal = {Organic \& Biomolecular Chemistry},
	volume = {21},
	year = {2023},
	month = {JUL},
	pages = {5671-5690},
	type = {Review},
	abstract = {<p>
	Pyridine and its reduced form (piperidine) are the most common nitrogen heterocycles in FDA-approved drugs. Additionally, their presence in alkaloids, ligands for transition metals, catalysts, and organic materials with various properties makes them among the most important structural cores. Despite its importance, direct and selective functionalization of pyridine remains scarce due to its electron-poor nature and nitrogen coordination power. Instead, functionalized pyridine rings were primarily constructed from suitably substituted acyclic precursors. The focus on sustainable chemistry with minimum waste generation encourages chemists to develop direct C-H functionalization. This review summarizes different approaches to tackle the reactivity and regio- and stereoselectivity aspects for direct pyridine C-H functionalization.</p>
},
	issn = {1477-0520},
	doi = {10.1039/d3ob00799e},
	author = {Maity, Susmita and Bera, Asish and Bhattacharjya, Ayantika and Maity, Pradip}
}
