@article {47102,
	title = {Visible-light-induced controlled oxidation of N-substituted 1,2,3,4-tetrahydroisoquinolines for the synthesis of 3,4-dihydroisoquinolin-1(2h)-ones and isoquinolin-1(2H)-ones},
	journal = {Advanced Synthesis \& Catalysis},
	volume = {363},
	year = {2021},
	month = {MAR },
	pages = {1390-1400},
	type = {Article},
	abstract = {<p>A visible light-rose bengal-TBHP mediated, controlled oxidation of N-substituted 1,2,3,4-tetrahydroisoquinolines is developed for the synthesis of 3,4-dihydroisoquinolin-1(2H)-ones and isoquinolin-1(2H)-ones. The present method feature{\textquoteright}s a broad substrate scope, good functional group tolerances, and the products were prepared in good to excellent yields. The developed methodology further demonstrated in the synthesis of isoindolo[2,1-b] isoquinolin-5(7H)-one (topoisomerase-I inhibitor).</p>
},
	keywords = {2, 3, 4-Dihydroisoquinolin-1(2H)-one, 4-tetrahydroisoquinolines, Isoquinolin-1(2H)-one, N-substituted 1, Oxidation, Photocatalysis},
	issn = {1615-4150},
	doi = {10.1002/adsc.202001266, Early Access Date = JAN 2021},
	author = {Bansode, Ajay H. and Suryavanshi, Gurunath}
}
@article {49412,
	title = {Hypervalent-iodine-mediated base-free oxidative olefination of benzylic amines to access α,β-unsaturated ketones},
	journal = {Synlett},
	year = {2024},
	month = {AUG},
	type = {Article; Early Access},
	abstract = {<p>
	We report a one-pot base-free protocol for the oxidative olefination of benzylic amines promoted by a hypervalent iodine reagent for the synthesis of alpha,beta-unsaturated ketones. Mechanistically, (diacetoxyiodo)benzene oxidizes the benzylic amine to the corresponding imine, which, on reaction with a phenacyl(triphenyl)phosphonium bromide salt and an in situ generated acetoxy anion leads to an alpha,beta-unsaturated ketone. A wide range of alpha,beta-unsaturated ketones were easily accessed through direct oxidative olefination of substituted benzylic amines in good to excellent yields and with high E -selectivity.</p>
},
	keywords = {benzylic amines, enones, hypervalent iodine, olefination, Oxidation},
	issn = {0936-5214},
	doi = {10.1055/s-0043-1775392},
	author = {Rupanawar, Bapurao D. and Bansode, Ajay H. and Suryavanshi, Gurunath}
}
