@article {47082,
	title = {Bimetallic nano alloy architecture on a special polymer: Ni or Cu merged with Pd for the promotion of the Mizoroki-Heck reaction and the Suzuki-Miyaura coupling},
	journal = {Journal of Chemical Sciences},
	volume = {133},
	year = {2021},
	month = {FEB },
	pages = {8},
	type = {Article},
	abstract = {<p>Novel Ni-Pd and Cu-Pd bimetallic nano alloys was designed and heterogenized on the highly robust ABPBI [poly(2,5-benzimidazole)] polymer in high yields using NaBH4 as reducing agent. These were versatile ligand free catalysts for the Mizoroki-Heck reaction and Suzuki-Miyaura coupling. The bimetallic Ni-Pd-ABPBI catalyst for the Mizoroki-Heck reaction of 4-iodo anisole could be recycled 5 times with high yields. Aryl bromides could also be activated for the Mizoroki-Heck reaction using Cu-Pd-ABPBI NP catalysts, with moderate yields. Graphic abstractSynopsis Novel bimetallic Ni-Pd and Cu-Pd nano alloys, heterogenized on the robust ABPBI [poly(2,5-benzimidazole)] polymer using NaBH4 as reducing agent, is described. These were versatile ligand free, noble metal conservative catalysts, for the Mizoroki-Heck reaction and the Suzuki-Miyaura coupling. Aryl bromides were activated for the Mizoroki-Heck reaction using the Cu-Pd-ABPBI catalyst.</p>
},
	keywords = {Bimetallic nano alloys, Cu-Pd-ABPBI, Mizoroki-Heck reaction, Ni-Pd-ABPBI, Suzuki coupling},
	issn = {0974-3626},
	doi = {10.1007/s12039-020-01870-6},
	author = {Patil, Vijay P. and Kashid, Abhijit A. and Solanki, Bhanupratap S. and Kharul, Ulhas K. and Iyer, Suresh}
}
@article {46754,
	title = {Bimetallic Ni-Pd synergism-mixed metal catalysis of the mizoroki-heck reaction and the suzuki-miyaura coupling of aryl bromides},
	journal = {Catalysis Letters},
	volume = {151},
	year = {2021},
	month = {FEB},
	pages = {353-358},
	type = {Article},
	abstract = {<p>A combination of Pd and Ni complexes activated aryl bromides for the thermal Mizoroki-Heck reaction and Suzuki coupling giving high yields in short reaction times. A thermal redox mechanism probably occurs whereby Ni complex transfers electron and reduces the Pd (II) to Pd (0) which then takes the reactants through the standard protocol of oxidative-addition, migratory insertion and reductive elimination, typical for the Mizoroki-Heck reaction and the Suzuki coupling. [GRAPHICS] .</p>
},
	keywords = {Bimetallic catalysis, Mizoroki-Heck, Nickel complexes, Pd(OAc)2, Suzuki coupling},
	issn = {1011-372X},
	doi = {10.1007/s10562-020-03330-9, Early Access Date = AUG 2020},
	author = {Kashid, Abhijit A. and Patil, Dharmaraj J. and Mali, Ramling D. and Patil, Vijay P. and Neethu, T. V. and Meroliya, Heena K. and Waghmode, Shobha A. and Iyer, Suresh}
}
