@article {49004,
	title = {Chemically gradient hydrogen-bonded organic framework crystal film},
	journal = {Angewandte Chemie-International Edition},
	volume = {62},
	year = {2023},
	month = {JUL },
	type = {Article},
	abstract = {<p>
	Hydrogen-bonded organic frameworks (HOFs) are ordered supramolecular solid structures, however, nothing much explored as centimetre-scale self-standing films. The fabrication of such crystals comprising self-supported films is challenging due to the limited flexibility and interaction of the crystals, and therefore studies on two-dimensional macrostructures of HOFs are limited to external supports. Herein, we introduce a novel chemical gradient strategy to fabricate a crystal-deposited HOF film on an in situ-formed covalent organic polymer film (Tam-Bdca-CGHOF). The fabricated film showed versatility in chemical bonding along its thickness from covalent to hydrogen-bonded network. The kinetic-controlled Tam-Bdca-CGHOF showed enhanced proton conductivity (8.3x10(-5) S cm(-1)) compared to its rapid kinetic analogue, Tam-Bdca-COP (2.1x10(-5) S cm(-1)), which signifies the advantage of bonding-engineering in the same system.</p>
},
	keywords = {Chemical Gradience, Crystal Films, Free-Standing Films, hydrogen-bonded organic framework, Interfacial Chemistry, proton conductivity},
	issn = {1433-7851},
	doi = {10.1002/anie.202304313},
	author = {Mohammed, Abdul Khayum and Raya, Jesus and Pandikassala, Ajmal and Addicoat, Matthew A. and Gaber, Safa and Aslam, Mohamed and Ali, Liaqat and Kurungot, Sreekumar and Shetty, Dinesh}
}
@article {48333,
	title = {Salicylaldehydate coordinated two-dimensional-conjugated metal-organic frameworks},
	journal = {Chemical Communications},
	volume = {59},
	year = {2023},
	month = {FEB },
	pages = {2608-2611},
	type = {Article},
	abstract = {<p>
	A novel class of copper-based 2D-c-MOF was synthesized from 1,3,5-triformylphloroglucinol using green mechano-chemistry. Herein, metal coordination with the salicylaldehyde functional moiety was explored for the first time in MOFs. Moreover, an intrinsic semiconductive copper-based SA-MOF thin film was fabricated using an in situ salt-free method at room temperature.</p>
},
	issn = {1359-7345},
	doi = {10.1039/d2cc06283f},
	author = {Mohammed, Abdul Khayum and Pena-Sanchez, Pilar and Pandikassala, Ajmal and Gaber, Safa and AlKhoori, Ayesha A. and Skorjanc, Tina and Polychronopoulou, Kyriaki and Kurungot, Sreekumar and Gandara, Felipe and Shetty, Dinesh}
}
@article {49245,
	title = {MOFite: a high-density lithiophilic and scalable metal-organic framework anode for rechargeable lithium-ion battery},
	journal = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION},
	volume = {63},
	year = {2024},
	month = {OCT },
	type = {Journal Article},
	keywords = {conjugated MOF, Energy storage, lithium ion battery, Metal-organic framework, scalable synthesis},
	issn = {1433-7851},
	doi = {10.1002/anie.202409256},
	author = {Gaber, Safa and Mohammed, Abdul Khayum and Javaregowda, Bharathkumar H. and Martinez, Jose Ignacio and Sanchez, Pilar Pena and Gandara, Felipe and Krishnamoorthy, Kothandam and Shetty, Dinesh}
}
