@article { ISI:000363828500010,
	title = {Efficient organocatalytic route for asymmetric total synthesis of stagonolide F},
	journal = {Tetrahedron Letters},
	volume = {56},
	number = {45},
	year = {2015},
	month = {NOV},
	pages = {6207-6209},
	publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
	address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
	abstract = {<p>A stereoselective total synthesis of Stagonolide F (98\% ee) is described employing asymmetric alpha-aminooxylation, Jorgensen{\textquoteright}s asymmetric epoxidation, Brown asymmetric allylation, Steglich esterification and ring closing metathesis as key steps. The use of organocatalytic alpha-aminooxylation and Jorgensen{\textquoteright}s asymmetric epoxidation of aldehydes for the introduction of chirality makes this approach more attractive. (C) 2015 Elsevier Ltd. All rights reserved.</p>},
	keywords = {alpha-Aminooxylation, Jorgensens{\textquoteright}s asymmetric epoxidation, Macrolide, Ring-closing metathesis, Total synthesis},
	issn = {0040-4039},
	doi = {10.1016/j.tetlet.2015.09.082},
	author = {Shelke, Anil M. and Suryavanshi, Gurunath}
}
@article {48008,
	title = {Studies toward the total synthesis of (+)-neopeltolide using N-heterocyclic carbene-catalyzed oxo-acyloxylation/reductive oxa-Michael addition strategy},
	journal = {Bulletin of the Korean Chemical Society},
	volume = {43},
	year = {2022},
	month = {OCT},
	pages = {1169-1172},
	type = {Article},
	abstract = {<p>
	This article describes a concise synthesis of two important fragments (tetrahydropyran [THP] and ketone moieties) of the cytotoxic macrolide (+)-neopeltolide in 10 long linear steps in enantiomerically pure form. Asymmetric Keck allylation to install the required C11 and C13 stereocenters, N-heterocyclic carbene (NHC)-catalyzed oxoacyloxylation to functionalize alkenes, and reductive oxa-Michael addition to construct 2,6-difunctionalized THP unit intramolecularly are the important steps in synthetic efforts. Finally, Keck asymmetric allylation and Lewis acid-catalyzed diastereoselective allylation of the aldehyde were sequentially employed to establish the stereocenters at C11 and C13 positions, respectively.</p>
},
	keywords = {(+)-neopeltolide, Keck allylation, Macrolide, NHC-catalyzed oxoacyloxylation, reductive oxa-Michael addition},
	issn = {0253-2964},
	doi = {10.1002/bkcs.12604},
	author = {Reddi, Rambabu N. and Sudalai, Arumugam and Jo, Changbum}
}
