@article { ISI:000233432200006,
	title = {Carbonylation of alkynes, alkenes and alcohols using metal complex catalysts},
	journal = {Catalysis Surveys from Asia},
	volume = {9},
	number = {3},
	year = {2005},
	month = {SEP},
	pages = {193-205},
	publisher = {SPRINGER/PLENUM PUBLISHERS},
	address = {233 SPRING ST, NEW YORK, NY 10013 USA},
	abstract = {<p>Carbonylation of olefins, alcohols and halides using homogeneous as well as heterogeneous catalysts has been discussed. Highlights of contributions on the activity, selectivity and stability of catalysts for carbonylation reactions are discussed. Kinetics and mechanism including characterization of the intermediate catalytic species has also been reviewed. The performance of anchored Pd complexes on mesoporous supports (MCM-41 and MCM-48), water soluble Pd complexes and supported Pd catalysts in carbonylation of aryl alcohols and olefins has been discussed in the context of catalyst-product separation. Some aspects of kinetic modelling and reaction engineering of these multiphase catalytic reactions have also been reviewed.</p>},
	keywords = {Carbonylation, catalysis, Heterogenization, homogeneous, Palladium},
	issn = {1571-1013},
	doi = {10.1007/s10563-005-7556-x},
	author = {Sarkar, B. R. and Chaudhari, Raghunath V.}
}
@article {46889,
	title = {Kinetics of hydroformylation of camphene using rhodium-phosphite catalyst},
	journal = {International Journal of Chemical Kinetics},
	volume = {52},
	year = {2020},
	month = {JUL},
	pages = {485-495},
	type = {Article},
	abstract = {<p>Kinetics of hydroformylation of camphene was investigated in the presence of [Rh(CO)(2)(acac)]/P(OPh)(3) catalyst in a temperature range of 363-383 K. The influence of parameters such as stirring speed, camphene, catalyst, ligand concentrations, and partial pressures of H-2 and CO on the activity and selectivity of the catalyst has been studied. The rate showed a first-order dependence with respect to catalyst and camphene concentrations. The effect of partial pressure of hydrogen showed fractional order dependence. The plots of rate versus excess ligand, that is, (P(OPh)(3)) concentration and rate versus CO partial pressure passed through maxima and showed typical substrate/ligand inhibited kinetics. An empirical rate equation has been proposed and found to be in good agreement with the observed rate data. The kinetic parameters and activation energy were also evaluated.</p>
},
	keywords = {camphene, homogeneous, Hydroformylation, kinetics, rhodium-phosphite},
	issn = {0538-8066},
	doi = {10.1002/kin.21364, Early Access Date = APR 2020},
	author = {Pagar, Nitin S. and Rajurkar, Kalpendra B. and Deshpande, Raj M.}
}
