Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt
| Title | Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt |
| Publication Type | Journal Article |
| Year of Publication | 2020 |
| Authors | Rysak, V, Dixit, R, Trivelli, X, Merle, N, Agbossou-Niedercorn, F, Vanka, K, Michon, C |
| Journal | Catalysis Science & Technology |
| Volume | 10 |
| Issue | 14 |
| Pagination | 4586-4592 |
| Date Published | JUL |
| Type of Article | Article |
| ISSN | 2044-4753 |
| Abstract | We report the catalytic and transition metal-free reductive deoxygenation of esters to ethers through the use of a hydrosilane and a fluorinated borate BArF salt as a catalyst. Experimental and theoretical studies support the role of noncovalent interactions between the fluorinated catalyst, the hydrosilane and the ester substrate in the reaction mechanism. |
| DOI | 10.1039/d0cy00775g |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 5.721 |
Divison category:
Physical and Materials Chemistry