Copper(I) bromide-catalyzed carbonylative coupling of aryl halides with phenols, alcohols and amines using sodium cyanide as C-1 source: a synthesis of carboxylic acid derivatives
| Title | Copper(I) bromide-catalyzed carbonylative coupling of aryl halides with phenols, alcohols and amines using sodium cyanide as C-1 source: a synthesis of carboxylic acid derivatives |
| Publication Type | Journal Article |
| Year of Publication | 2014 |
| Authors | Prasad, PK, Sudalai, A |
| Journal | Advanced Synthesis & Catalysis |
| Volume | 356 |
| Issue | 10 |
| Pagination | 2231-2238 |
| Date Published | JUL |
| ISSN | 1615-4150 |
| Keywords | anhydrides, C-1 building blocks, isochroman-1-ones, lactams, lactones |
| Abstract | A new ``carbon monoxide-free'' synthesis of carboxylate derivatives via carbonylative coupling of aryl bromides with phenols, alcohols, amines and acids in the presence of copper(I) bromide as catalyst and sodium cyanide in a stoichiometric amount has been developed. Its intramolecular version provides for the preparation of lactones (e.g., isochroman-1-ones and isobenzfuranones), imides, anhydrides and lactams in excellent yields (73-96%). |
| DOI | 10.1002/adsc.201301155 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.453 |
Divison category:
Chemical Engineering & Process Development