Cross-coupling reactions of aryldiazonium salts with allylsilanes under merged gold/visible-light photoredox catalysis
| Title | Cross-coupling reactions of aryldiazonium salts with allylsilanes under merged gold/visible-light photoredox catalysis |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Akram, MO, Mali, PS, Patil, NT |
| Journal | Organic Letters |
| Volume | 19 |
| Issue | 12 |
| Pagination | 3075-3078 |
| Date Published | JUN |
| Type of Article | Article |
| Abstract | A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merged gold/photoredox catalysis is described. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes transmetalation with allyltrimethylsilane to form allylarenes. |
| DOI | 10.1021/acs.orglett.7b01148 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.732 |
Divison category:
Organic Chemistry