Electrochemically enabled (3+2) cycloaddition of unbiased alkenes and β-dicarbonyls
| Title | Electrochemically enabled (3+2) cycloaddition of unbiased alkenes and β-dicarbonyls |
| Publication Type | Journal Article |
| Year of Publication | 2024 |
| Authors | Suryawanshi, SM, Sahoo, S, Shaligram, PS, Manna, N, Samanta, RC |
| Journal | Chemical Communications |
| Volume | 60 |
| Issue | 45 |
| Pagination | 5836-5839 |
| Date Published | MAY |
| Type of Article | Article |
| ISSN | 1359-7345 |
| Keywords | 1, 3-DICARBONYL COMPOUNDS, DIHYDROFURANS, FACILE SYNTHESIS |
| Abstract | A (3+2) cycloaddition between unbiased alkenes and 1,3-dicarbonyls is accomplished by judicious choice of electrode material and electrocatalyst to access dihydrofuran derivatives. A fluorinated porous carbon electrode with appropriate thickness governs unprecedented reactivity. This methodology eliminates the necessity for any stabilizing group within the alkene substrate. This is a rare example of the annulation of unbiased internal and terminal alkenes with cyclic and acyclic beta-dicarbonyls. |
| DOI | 10.1039/d4cc01263a |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.9 |
Divison category:
Organic Chemistry
Physical and Materials Chemistry
Database:
Web of Science (WoS)