NaIO4/LiBr-mediated aziridination of olefins using chloramine-T
| Title | NaIO4/LiBr-mediated aziridination of olefins using chloramine-T |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Karabal, PU, Chouthaiwale, PV, Shaikh, TM, Suryavanshi, G, Sudalai, A |
| Journal | Tetrahedron Letters |
| Volume | 51 |
| Issue | 49 |
| Pagination | 6460-6462 |
| Date Published | DEC |
| ISSN | 0040-4039 |
| Keywords | Aziridination, Chloramine-T, Lithium bromide, Olefin, Sodium metaperiodate |
| Abstract | A new milder protocol for aziridination of a variety of olefins has been described. The process employs catalytic amount of sodium metaperiodate (NaIO4) as an oxidant and LiBr and chloramine-T as the bromine and nitrogen sources, respectively. Interestingly, the formation of aziridine products in all the cases studied takes place presumably through a process of 1,2-aminobromination of alkenes. (C) 2010 Elsevier Ltd. All rights reserved. |
| DOI | 10.1016/j.tetlet.2010.10.005 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.618 |
Divison category:
Chemical Engineering & Process Development