Organo-photoredox catalyzed oxidative dehydrogenation of N-heterocycles
| Title | Organo-photoredox catalyzed oxidative dehydrogenation of N-heterocycles |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Sahoo, MK, Jaiswal, G, Rana, J, Balaraman, E |
| Journal | Chemistry-A European Journal |
| Volume | 23 |
| Issue | 57 |
| Pagination | 14167-14172 |
| Date Published | OCT |
| Type of Article | Article |
| Abstract | We report here for the first time the catalytic oxidative dehydrogenation of N-heterocycles by a visible-light organo-photoredox catalyst with low catalyst loading (0.1-1mol%). The reaction proceeds efficiently under base- and additive-free conditions with ambient air at room temperature. The utility of this benign approach is demonstrated by the synthesis of various pharmaceutically relevant N-heteroarenes such as quinoline, quinoxaline, quinazoline, acridine, and indole. |
| DOI | 10.1002/chem.201703642 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 5.317 |
Divison category:
Catalysis and Inorganic Chemistry