Scandium triflate catalyzed unexpected cleavage of C-C bonds in ynones
| Title | Scandium triflate catalyzed unexpected cleavage of C-C bonds in ynones |
| Publication Type | Journal Article |
| Year of Publication | 2016 |
| Authors | Kavthe, RD, Bansode, AH, Patil, NT |
| Journal | Arkivoc |
| Issue | 2 |
| Pagination | 223-232 |
| Date Published | NOV |
| ISSN | 1551-7004 |
| Keywords | C-C bond cleavage, Esters, Ketones, scandium triflate, ynones |
| Abstract | An unexpected C-C bond cleavage in ynones in the presence of catalytic amounts of Sc(OTf)(3) in methanol under microwave irradiation has been discussed. The effect of substituent on the regioselectivity of C-C bond cleavage has carefully been addressed by employing various ynones derivatives. The mechanism has been proposed for the observed regioselectivity. |
| DOI | 10.3998/ark.5550190.p009.244 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 1.177 |
Divison category:
Organic Chemistry