Stabilization of graphene quantum dots (GQDs) by encapsulation inside zeolitic imidazolate framework nanocrystals for photoluminescence tuning
| Title | Stabilization of graphene quantum dots (GQDs) by encapsulation inside zeolitic imidazolate framework nanocrystals for photoluminescence tuning |
| Publication Type | Journal Article |
| Year of Publication | 2013 |
| Authors | Biswal, BP, Shinde, DB, Pillai, VK, Banerjee, R |
| Journal | Nanoscale |
| Volume | 5 |
| Issue | 21 |
| Pagination | 10556-10561 |
| Date Published | SEP |
| ISSN | 2040-3364 |
| Abstract | Luminescent graphene quantum dots (GQDs) are encapsulated and stabilized in Zeolitic Imidazolate Framework (ZIF-8) nanocrystals. The GQDs are well confined due to the adsorption on the growing face of the ZIF-8 nanocrystals and have a profound effect on the shape of the nanocrystals from rhombic dodecahedron to spherical. Stabilizing GQDs inside the ZIF-8 nanocrystals results in tailoring of the photoluminescence emission (ca. 32 nm, bathochromic shift) of the GQD@ZIF-8 nanocrystal composite even after 3 months of aging under normal laboratory conditions. Also the water adsorption (at STP) capacity increased for the GQD@ ZIF-8 composite as compared to the pristine ZIF-8. |
| DOI | 10.1039/c3nr03511e |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.739 |
Divison category:
Physical and Materials Chemistry
