Natural kaolinitic clay: a remarkable catalyst for highly regioselective chlorination of arenes with Cl-2 or SO2Cl2
| Title | Natural kaolinitic clay: a remarkable catalyst for highly regioselective chlorination of arenes with Cl-2 or SO2Cl2 |
| Publication Type | Journal Article |
| Year of Publication | 2006 |
| Authors | Jayachandran, B, Phukan, P, Daniel, T, Sudalai, A |
| Journal | Indian Journal of Chemistry Section B-Organic Chemistry Including Medicinal Chemistry |
| Volume | 45 |
| Issue | 4 |
| Pagination | 972-975 |
| Date Published | APR |
| Type of Article | Article |
| ISSN | 0376-4699 |
| Keywords | Aniline, chlorination, chlorine, ortho-chloroaniline, sulfuryl chloride |
| Abstract | Natural kaolinitic clay containing transition metals such as Fe and Ti in its lattice has been found to exhibit unusual regioselectivity in the liquid-phase chlorination of arenes with either Cl-2 or SO2Cl2 as the chlorinating agent para-Chlorinated products are predominant for most of the substrates with an exceptional case of ortho-selectivity for the chlorination of aniline. |
| Type of Journal (Indian or Foreign) | Indian |
| Impact Factor (IF) | 0.471 |
Divison category:
Chemical Engineering & Process Development
