New synthetic approach to a [1.1.6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis
| Title | New synthetic approach to a [1.1.6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis |
| Publication Type | Journal Article |
| Year of Publication | 2005 |
| Authors | Kotha, S, Mandal, K, Arora, KK, Pedireddi, R |
| Journal | Advanced Synthesis & Catalysis |
| Volume | 347 |
| Issue | 9 |
| Pagination | 1215-1218 |
| Date Published | JUL |
| ISSN | 1615-4150 |
| Keywords | Cyclophanes, olefin metathesis, Palladium, ruthenium, Suzuki-Miyaura cross-coupling |
| Abstract | The synthesis of a [1.1.6] metapara cyclophane derivative, 1,5(1,4),3(1,3)-tribenzenacycloun-decaphan-8-ene-6,11-dione, has been achieved via the Suzuki-Miyaura cross-coupling of alpha,alpha'-dibromo-m-xylene with an arylboronic acid derivative followed by an allylation and ring-closing metathesis reaction sequence. |
| DOI | 10.1002/adsc.200404373 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.453 |
Divison category:
Organic Chemistry