Highly active recyclable SBA-15-EDTA-Pd catalyst for Mizoroki-Heck, Stille and Kumada C-C coupling reactions
| Title | Highly active recyclable SBA-15-EDTA-Pd catalyst for Mizoroki-Heck, Stille and Kumada C-C coupling reactions |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Rathod, J, Sharma, P, Pandey, P, Singh, AP, Kumar, P |
| Journal | Journal of Porous Materials |
| Volume | 24 |
| Issue | 4 |
| Pagination | 837-846 |
| Date Published | AUG |
| Type of Article | Article |
| Abstract | Highly efficient SBA-15-EDTA-Pd(11) heterogeneous catalyst was synthesized by covalent anchoring Pd-EDTA complex over organo-modified surface of SBA-15. SBA-15-EDTA-Pd(11) catalyst was found to exhibit excellent catalytic activity in appreciable yield for Heck, Stille and Kumada cross-coupling reactions. Catalytic system exhibited excellent activity for completion of reaction, isolation, Pd loading (0.87 mmol%) and yields of products as compared to earlier reported heterogeneous supported Pd catalysts. Covalently anchored heterogeneous SBA-15-EDTA-Pd(11) catalyst can be recycled for more than five times without noticeable loss in activity and selectivity. |
| DOI | 10.1007/s10934-016-0323-8 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 1.385 |
Divison category:
Catalysis and Inorganic Chemistry
Organic Chemistry