Exploring the gem-dimethyl effect in the formation of imine-based macrocycles and cages
| Title | Exploring the gem-dimethyl effect in the formation of imine-based macrocycles and cages |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Madhu, S, Rashmi, EV, Gonnade, RGhanshyam, Sanjayan, GJ |
| Journal | New Journal of Chemistry |
| Volume | 17 |
| Issue | 41 |
| Pagination | 8721-8724 |
| Date Published | JUL |
| Type of Article | Article |
| Abstract | Using the gem-dimethyl effect as a platform, a variety of organic [2+2] macrocycles and [2+3] cofacial cages was obtained in high yields. Imine-based macrocyclization could be performed even at high concentrations (0.5 to 1.0 M), via instant mixing of aldehydes and amines. |
| DOI | 10.1039/C7NJ02069D |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.269 |
Divison category:
Center for Material Characterization (CMC)
Organic Chemistry