Silver sequestration of halides for the activation of Pd(OAc) 2 catalyzed Mizoroki-Heck reaction of 1,1 and 1,2 - Disubstituted alkenes: Ag Sequestration for Pd catalyzed Heck reaction- disubstituted alkenes
| Title | Silver sequestration of halides for the activation of Pd(OAc) 2 catalyzed Mizoroki-Heck reaction of 1,1 and 1,2 - Disubstituted alkenes: Ag Sequestration for Pd catalyzed Heck reaction- disubstituted alkenes |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Bangar, PG, Jawalkar, PR, Dumbre, S, Patil, D, Iyer, S |
| Journal | Applied Organometallic Chemistry |
| Volume | 32 |
| Issue | 3 |
| Pagination | e4159 |
| Date Published | NOV |
| ISSN | 0268-2605 |
| Keywords | 1, 1-disubstituted alkenes, 2-disubstituted alkenes, AgBF4, AgOAc, Mizoroki-Heck reaction |
| Abstract | A ligand free catalytic system consisting of Pd(OAc)2 (cat) and stoichiometric quantities of silver salts, AgOAc or AgBF4, exhibit high efficiency in the Mizoroki-Heck arylation, transforming aryl iodides and 1,1 as well as 1,2 disubstituted alkenes into 1,1,2 – trisubstituted aryl alkenes in excellent yields in very short reaction times. |
| DOI | 10.1002/aoc.4159 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.319 |
Divison category:
Organic Chemistry